Be cautious with high-strength DEET and a hammock. 100% DEET will weaken nylon over time, and your behind is relying on that nylon to hold you up.
That being said, I've used concentrations up to and including 100% during the day before sleeping in my hammock without ill effect. Just before getting into bed when it's hot out, I usually take a field bath anyway, though, so that might have something to do with it.
Just a thought.
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