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  1. #261
    Senior Member Knotty's Avatar
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    Denatured alcohol might be worth a try but only with the dunk and squeeze method. Would probably evaporate to fast for brushing on.

    I think that even when we use mineral spirits the silicone caulk doesn't actually dissolve into it. I believe what we're really doing is making an emulsion, which is why thorough mixing is key. Think salad dressing...oil and vinegar don't mix but but you can make an emulsion from the two in order to keep them from separating for a little while.

    I there a chemical engineer in the house...MacEntyre?
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  2. #262
    MacEntyre's Avatar
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    I think you are correct, Knotty, because silicon we use for waterproofing is really a silicon polymer called Polydimethylsiloxane (PDMS) or dimenthicone, an inert, non toxic, non flammable substance with unusual flow properties. It's used everywhere... silly putty, caulk, adhesives, polyurethanes, shampoo, food, contact lenses.

    Aqueous solvents, like alcohol, do not dissolve or diffuse into silicon polymer. Organic solvents don't dissolve silicon polymers, but they do diffuse into it and make it swell, some to a greater extent than others. So, we are making a slurry, as you said, but solvents that diffuse into the silicon will take longer to evaporate out. Mineral spirits are not among the organic solvents that swell PDMS a lot.
    - MacEntyre
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  3. #263
    Senior Member Knotty's Avatar
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    Mac - You're the man. That's one solid answer. Thanks.
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  4. #264
    Senior Member 1022's Avatar
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    Quote Originally Posted by MacEntyre View Post
    I think you are correct, Knotty, because silicon we use for waterproofing is really a silicon polymer called Polydimethylsiloxane (PDMS) or dimenthicone, an inert, non toxic, non flammable substance with unusual flow properties. It's used everywhere... silly putty, caulk, adhesives, polyurethanes, shampoo, food, contact lenses.

    Aqueous solvents, like alcohol, do not dissolve or diffuse into silicon polymer. Organic solvents don't dissolve silicon polymers, but they do diffuse into it and make it swell, some to a greater extent than others. So, we are making a slurry, as you said, but solvents that diffuse into the silicon will take longer to evaporate out. Mineral spirits are not among the organic solvents that swell PDMS a lot.
    Now that is an answer !
    very informative, thanks

  5. #265
    Senior Member cosmicmiami's Avatar
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    Quote Originally Posted by MacEntyre View Post
    That's because denatured alcohol (ethanol) and mineral spirits (petroleum distillates) are totally different things.
    I'm familiar with the differences between the two, polar solvent vs. hydrocarbon. One gets 3% foam the other 6%
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  6. #266
    MacEntyre's Avatar
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    So, cosmicmiami, did you use denatured alcohol or mineral spirits?
    - MacEntyre
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  7. #267
    Senior Member cosmicmiami's Avatar
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    Quote Originally Posted by MacEntyre View Post
    I think you are correct, Knotty, because silicon we use for waterproofing is really a silicon polymer called Polydimethylsiloxane (PDMS) or dimenthicone, an inert, non toxic, non flammable substance with unusual flow properties. It's used everywhere... silly putty, caulk, adhesives, polyurethanes, shampoo, food, contact lenses.

    Aqueous solvents, like alcohol, do not dissolve or diffuse into silicon polymer. Organic solvents don't dissolve silicon polymers, but they do diffuse into it and make it swell, some to a greater extent than others. So, we are making a slurry, as you said, but solvents that diffuse into the silicon will take longer to evaporate out. Mineral spirits are not among the organic solvents that swell PDMS a lot.
    For a minute I thought I was watching BTTF and listening to Dr. Emmett Brown.

    I'll try the denatured on a small patch and see what happens.
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  8. #268
    Senior Member cosmicmiami's Avatar
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    Quote Originally Posted by MacEntyre View Post
    So, cosmicmiami, did you use denatured alcohol or mineral spirits?
    I used spirits first. Worked pretty well. Need to go back and do the seams.
    Health nuts are going to feel stupid someday, lying in hospitals dying of nothing.
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  9. #269
    Senior Member harrell79cj5's Avatar
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    Anybody that did this to a tarp or some other gear a while back have any report on longevity of the treatment?

  10. #270
    Senior Member Rain Man's Avatar
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    Talking

    Quote Originally Posted by MacEntyre View Post
    It's used everywhere... silly putty, caulk, adhesives, polyurethanes, shampoo, food, contact lenses.

    Okay, you've got my interest piqued!!! How do I make some DIY contact lenses with this stuff?! I could save tons in the long run, I bet!

    Rain Man

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    "You can stand tall without standing on someone. You can be a victor without having victims." --Harriet Woods

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