Denatured alcohol might be worth a try but only with the dunk and squeeze method. Would probably evaporate to fast for brushing on.
I think that even when we use mineral spirits the silicone caulk doesn't actually dissolve into it. I believe what we're really doing is making an emulsion, which is why thorough mixing is key. Think salad dressing...oil and vinegar don't mix but but you can make an emulsion from the two in order to keep them from separating for a little while.
I there a chemical engineer in the house...MacEntyre?
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